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Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions
Electronic differentiations in Pd-catalyzed allylic substitutions are assessed computationally from transition structure models with electronically modified phospha-benzene-pyridine ligands. Although donor/acceptor substitutions at P and N ligand sites were expected to increase the site selectivity,...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2175512/ https://www.ncbi.nlm.nih.gov/pubmed/17963482 http://dx.doi.org/10.1186/1860-5397-3-36 |