The first organocatalytic carbonyl-ene reaction: isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas

Intramolecular carbonyl ene reactions of highly activated enophiles can be catalysed by H-bonding thio-ureas to give tertiary alcohols in high yields without extensive isomerisation side products. An asymmetric variant of this reaction was realised using a chiral thiourea but was limited by low enan...

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Detalles Bibliográficos
Autores principales: Clarke, Matthew L, Jones, Charlotte E S, France, Marcia B
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2176055/
https://www.ncbi.nlm.nih.gov/pubmed/17868454
http://dx.doi.org/10.1186/1860-5397-3-24

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2176055/
https://www.ncbi.nlm.nih.gov/pubmed/17868454
http://dx.doi.org/10.1186/1860-5397-3-24

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