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Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air

A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et(3)B or Bu(3)B) and air.

Detalles Bibliográficos
Autores principales: Boivin, Jean, Nguyen, Van Tai
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2213661/
https://www.ncbi.nlm.nih.gov/pubmed/18076754
http://dx.doi.org/10.1186/1860-5397-3-45