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Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air
A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et(3)B or Bu(3)B) and air.
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2213661/ https://www.ncbi.nlm.nih.gov/pubmed/18076754 http://dx.doi.org/10.1186/1860-5397-3-45 |
| Sumario: | A new, mild, and environment friendly process for the reduction of S-alkyl-thionocarbonates, iodides and related compounds to the corresponding hydrocarbons at room temperature with good to excellent yields is described. This method uses a trialkylborane in excess (Et(3)B or Bu(3)B) and air. |
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