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Spectroscopic evidence for an all-ferrous [4Fe–4S](0) cluster in the superreduced activator of 2-hydroxyglutaryl-CoA dehydratase from Acidaminococcus fermentans

The key enzyme of the fermentation of glutamate by Acidaminococcus fermentans, 2-hydroxyglutarylcoenzyme A dehydratase, catalyzes the reversible syn-elimination of water from (R)-2-hydroxyglutaryl-coenzyme A, resulting in (E)-glutaconylcoenzyme A. The dehydratase system consists of two oxygen-sensit...

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Detalles Bibliográficos
Autores principales: Hans, Marcus, Buckel, Wolfgang, Bill, Eckhard
Formato: Texto
Lenguaje:English
Publicado: Springer-Verlag 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2359827/
https://www.ncbi.nlm.nih.gov/pubmed/18274792
http://dx.doi.org/10.1007/s00775-008-0345-z