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2D NMR Methods for Structural Delineation of Copper(II) Complexes of Penicillin and Pilocarpine
A method was developed for delineating the structure of paramagnetic metal complexes. The selective disappearance of cross-peaks in proton-carbon shift correlated 2D NMR maps was shown to uniquely depend upon the scalar and/or dipolar interaction between ligand nuclei and the unpaired electron(s), t...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Hindawi Publishing Corporation
1994
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2364899/ https://www.ncbi.nlm.nih.gov/pubmed/18476239 http://dx.doi.org/10.1155/MBD.1994.279 |