Electronic and Steric Effects in Gold(I) Phosphine Thiolate Complexes

The unusual yellow color of Au(2)(dppm)(SR)(2) (R = 4-tolyl; dppm = diphenylphosphinomethane) is attributed to a red-shift in the S→Au charge transfer caused by destabilization of the sulfur highest occupied molecular orbital (HOMO). Variable temperature experiments show two broad bands at -80°C in...

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Detalles Bibliográficos
Autores principales: Foley, Janet, Fort, Raymond C., McDougal, Katherine, Bruce, Mitchell R. M., Bruce, Alice E.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 1994
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2364921/
https://www.ncbi.nlm.nih.gov/pubmed/18476259
http://dx.doi.org/10.1155/MBD.1994.405

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2364921/
https://www.ncbi.nlm.nih.gov/pubmed/18476259
http://dx.doi.org/10.1155/MBD.1994.405

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