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Kinetic and High-Pressure Mechanistic Investigation of the Aqua Substitution in the Trans-Aquaoxotetracyano Complexes of Re(V) and Tc(V): Some Implications for Nuclear Medicine
A kinetic study of the aqua substitution in the [TcO(OH(2))(CN)(4)](−) complex by different thiourea ligands (TU = thiourea, NMTU = N-methyl thiourea, NNDMTU = N, N′-dimethylthiourea) yielded second-order formation rate constants (25°C) as follows [NNDMTU, NMTU, TU, respectively]: k(f) = 11.5 ± 0.1,...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Hindawi Publishing Corporation
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2367617/ https://www.ncbi.nlm.nih.gov/pubmed/18464928 http://dx.doi.org/10.1155/2008/745989 |