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Accurate stereochemistry for two related 22,26-epimino­cholestene derivatives

Regioselective opening of ring E of solasodine under various conditions afforded (25R)-22,26-epimino­cholesta-5,22(N)-di­ene-3β,16β-diyl diacetate (previously known as 3,16-diacetyl pseudosolasodine B), C(31)H(47)NO(4), or (22S,25R)-16β-hydr­oxy-22,26-epimino­cholesta-5-en-3β-yl acetate (a derivativ...

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Detalles Bibliográficos
Autores principales: Vega-Baez, José Luis, Sandoval-Ramírez, Jesús, Meza-Reyes, Socorro, Montiel-Smith, Sara, Gómez-Calvario, Victor, Bernès, Sylvain
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2467522/
https://www.ncbi.nlm.nih.gov/pubmed/18391392
http://dx.doi.org/10.1107/S0108270108005763