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Accurate stereochemistry for two related 22,26-epiminocholestene derivatives
Regioselective opening of ring E of solasodine under various conditions afforded (25R)-22,26-epiminocholesta-5,22(N)-diene-3β,16β-diyl diacetate (previously known as 3,16-diacetyl pseudosolasodine B), C(31)H(47)NO(4), or (22S,25R)-16β-hydroxy-22,26-epiminocholesta-5-en-3β-yl acetate (a derivativ...
Autores principales: | Vega-Baez, José Luis, Sandoval-Ramírez, Jesús, Meza-Reyes, Socorro, Montiel-Smith, Sara, Gómez-Calvario, Victor, Bernès, Sylvain |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2467522/ https://www.ncbi.nlm.nih.gov/pubmed/18391392 http://dx.doi.org/10.1107/S0108270108005763 |
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