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Diels-Alder reactions using 4,7-dioxygenated indanones as dienophiles for regioselective construction of oxygenated 2,3-dihydrobenz[f]indenone skeleton

Regioselective construction of 4,8,9-trioxygenated 2,3-dihydrobenz[f]indenones, key intermediates for the synthesis of kinamycin antibiotics, was achieved via Diels-Alder reactions (DAR) using 4,7-dioxygenated indanone-type compounds as dienophiles. Reaction of indanetrione with 1-methoxybutadiene g...

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Detalles Bibliográficos
Autores principales: Etomi, Natsuno, Kumamoto, Takuya, Nakanishi, Waka, Ishikawa, Tsutomu
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2486486/
https://www.ncbi.nlm.nih.gov/pubmed/18941487
http://dx.doi.org/10.3762/bjoc.4.15