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DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

We examined the catalytic enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones 1 with N-fluorobenzenesulfonimide (NFSI) by DBFOX-Ph/metal complexes under a variety of conditions. After optimization of the metal salts, solvents and additives, we found that the fluoro-2-thiazolidinones...

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Detalles Bibliográficos
Autores principales: Ishimaru, Takehisa, Shibata, Norio, Reddy, Dhande Sudhakar, Horikawa, Takao, Nakamura, Shuichi, Toru, Takeshi
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2486487/
https://www.ncbi.nlm.nih.gov/pubmed/18941488
http://dx.doi.org/10.3762/bjoc.4.16