Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates

We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution feature...

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Detalles Bibliográficos
Autores principales: Xu, Jun, Qiu, Xiao-Long, Qing, Feng-Ling
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2486488/
https://www.ncbi.nlm.nih.gov/pubmed/18941489
http://dx.doi.org/10.3762/bjoc.4.18

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2486488/
https://www.ncbi.nlm.nih.gov/pubmed/18941489
http://dx.doi.org/10.3762/bjoc.4.18

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