Control of asymmetric biaryl conformations with terpenol moieties: Syntheses, structures and energetics of new enantiopure C(2)-symmetric diols

New enantiopure, C(2)-symmetric biphenyl-2,2′-diols based on (−)-menthone (BIMOL), (−)-verbenone (BIVOL) and (−)-carvone (BICOL and hydrogenated BIMEOL), are accessible via short, synthetic routes. All diols form intramolecular hydrogen bonds and hence can be employed as chelating ligands for cataly...

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Detalles Bibliográficos
Autores principales: Alpagut, Y, Goldfuss, B, Neudörfl, J-M
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2511025/
https://www.ncbi.nlm.nih.gov/pubmed/18941496
http://dx.doi.org/10.3762/bjoc.4.25

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2511025/
https://www.ncbi.nlm.nih.gov/pubmed/18941496
http://dx.doi.org/10.3762/bjoc.4.25

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