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Control of asymmetric biaryl conformations with terpenol moieties: Syntheses, structures and energetics of new enantiopure C(2)-symmetric diols
New enantiopure, C(2)-symmetric biphenyl-2,2′-diols based on (−)-menthone (BIMOL), (−)-verbenone (BIVOL) and (−)-carvone (BICOL and hydrogenated BIMEOL), are accessible via short, synthetic routes. All diols form intramolecular hydrogen bonds and hence can be employed as chelating ligands for cataly...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2511025/ https://www.ncbi.nlm.nih.gov/pubmed/18941496 http://dx.doi.org/10.3762/bjoc.4.25 |