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Compounds with a ‘stuffed’ anti-bixbyite-type structure, analysed in terms of the Zintl–Klemm and coordination-defect concepts
The bixbyite structure (Mn(2)O(3)) ([Image: see text]) is often described as a distorted face-centered cubic (f.c.c.) array of Mn atoms, with O atoms occupying 3/4 of the tetrahedral holes. The empty M (4) tetrahedra are centred at 16c. In anti-bixbyite structures (Mg(3)N(2)), cation vacancies are c...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2628973/ https://www.ncbi.nlm.nih.gov/pubmed/19155554 http://dx.doi.org/10.1107/S010876810803423X |