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Total Synthesis of Spirotenuipesines A and B

[Image: see text] Spirotenuipesines A and B, isolated from the entomopathogenic fungus Paecilomyces tenuipes by Oshima and co-workers, have been synthesized. The synthesis features the highly stereoselective construction of two vicinal all-carbon quaternary centers (C(5) and C(6)) via an intramolecu...

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Detalles Bibliográficos
Autores principales: Dai, Mingji, Krauss, Isaac J., Danishefsky, Samuel J.
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2008
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2646666/
https://www.ncbi.nlm.nih.gov/pubmed/18973385
http://dx.doi.org/10.1021/jo8016814