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Amine-Directed Hydroboration: Scope and Limitations

[Image: see text] Iodine activation induces intramolecular hydroboration of homoallylic and bis-homoallylic amine boranes with good to excellent control of regiochemistry compared to control experiments using excess THF•BH(3). Deuterium labeling and other evidence confirm that the iodine-induced hyd...

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Detalles Bibliográficos
Autores principales: Scheideman, Matthew, Wang, Guoqiang, Vedejs, Edwin
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2008
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2646876/
https://www.ncbi.nlm.nih.gov/pubmed/18549217
http://dx.doi.org/10.1021/ja0774663