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Total Syntheses of (+)- and (−)-Peribysin E
[Image: see text] A convergent, stereocontrolled route to either antipode of the cell adhesion inhibitor, peribysin E, has been achieved from carvone. Highlights of the synthesis include a Diels−Alder reaction to generate a cis-decalin framework, followed by semipinacol-type ring contraction to secu...
Autores principales: | Angeles, Angie R., Waters, Stephen P., Danishefsky, Samuel J. |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2646880/ https://www.ncbi.nlm.nih.gov/pubmed/18783227 http://dx.doi.org/10.1021/ja8048207 |
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