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Reduction of arenediazonium salts by tetrakis(dimethylamino)ethylene (TDAE): Efficient formation of products derived from aryl radicals

Tetrakis(dimethylamino)ethylene (TDAE 1), has been exploited for the first time as a mild reagent for the reduction of arenediazonium salts to aryl radical intermediates through a single electron transfer (SET) pathway. Cyclization of the aryl radicals produced in this way led, in appropriate substr...

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Detalles Bibliográficos
Autores principales: Mahesh, Mohan, Murphy, John A, LeStrat, Franck, Wessel, Hans Peter
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2649425/
https://www.ncbi.nlm.nih.gov/pubmed/19259337
http://dx.doi.org/10.3762/bjoc.5.1