Thiol−Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks

[Image: see text] Radical-mediated thiol−yne step-growth photopolymerizations are utilized to form highly cross-linked polymer networks. This reaction mechanism is shown to be analogous to the thiol−ene photopolymerization; however, each alkyne functional group is capable of consecutive reaction wit...

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Detalles Bibliográficos
Autores principales: Fairbanks, Benjamin D., Scott, Timothy F., Kloxin, Christopher J., Anseth, Kristi S., Bowman, Christopher N.
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2008
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2651690/
https://www.ncbi.nlm.nih.gov/pubmed/19461871
http://dx.doi.org/10.1021/ma801903w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2651690/
https://www.ncbi.nlm.nih.gov/pubmed/19461871
http://dx.doi.org/10.1021/ma801903w

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