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Thiol−Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks
[Image: see text] Radical-mediated thiol−yne step-growth photopolymerizations are utilized to form highly cross-linked polymer networks. This reaction mechanism is shown to be analogous to the thiol−ene photopolymerization; however, each alkyne functional group is capable of consecutive reaction wit...
Autores principales: | Fairbanks, Benjamin D., Scott, Timothy F., Kloxin, Christopher J., Anseth, Kristi S., Bowman, Christopher N. |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2651690/ https://www.ncbi.nlm.nih.gov/pubmed/19461871 http://dx.doi.org/10.1021/ma801903w |
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