Geometric and Electronic Structures of the Ni(I) and Methyl−Ni(III) Intermediates of Methyl-Coenzyme M Reductase

[Image: see text] Methyl-coenzyme M reductase (MCR) catalyzes the terminal step in the formation of biological methane from methyl-coenzyme M (Me-SCoM) and coenzyme B (CoBSH). The active site in MCR contains a Ni−F(430) cofactor, which can exist in different oxidation states. The catalytic mechanism...

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Detalles Bibliográficos
Autores principales: Sarangi, Ritimukta, Dey, Mishtu, Ragsdale, Stephen W.
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2009
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2667316/
https://www.ncbi.nlm.nih.gov/pubmed/19243132
http://dx.doi.org/10.1021/bi900087w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2667316/
https://www.ncbi.nlm.nih.gov/pubmed/19243132
http://dx.doi.org/10.1021/bi900087w

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