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Grunwald-Winstein Analysis - Isopropyl Chloroformate Solvolysis Revisited

Specific rates of solvolysis at 25 °C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at 40.0 °C are supplemented with two ad...

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Detalles Bibliográficos
Autores principales: D’Souza, Malcolm J., Reed, Darneisha N., Erdman, Kevin J., Kyong, Jin Burm, Kevill, Dennis N.
Formato: Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2672006/
https://www.ncbi.nlm.nih.gov/pubmed/19399225
http://dx.doi.org/10.3390/ijms10030862