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Grunwald-Winstein Analysis - Isopropyl Chloroformate Solvolysis Revisited
Specific rates of solvolysis at 25 °C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at 40.0 °C are supplemented with two ad...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International (MDPI)
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2672006/ https://www.ncbi.nlm.nih.gov/pubmed/19399225 http://dx.doi.org/10.3390/ijms10030862 |