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Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives

This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.

Detalles Bibliográficos
Autores principales: Rowlands, Gareth J, Seacome, Richard J
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2686273/
https://www.ncbi.nlm.nih.gov/pubmed/19478964
http://dx.doi.org/10.3762/bjoc.5.9