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Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives
This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2686273/ https://www.ncbi.nlm.nih.gov/pubmed/19478964 http://dx.doi.org/10.3762/bjoc.5.9 |
| _version_ | 1782167389094281216 |
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| author | Rowlands, Gareth J Seacome, Richard J |
| author_facet | Rowlands, Gareth J Seacome, Richard J |
| author_sort | Rowlands, Gareth J |
| collection | PubMed |
| description | This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported. |
| format | Text |
| id | pubmed-2686273 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-26862732009-05-28 Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives Rowlands, Gareth J Seacome, Richard J Beilstein J Org Chem Full Research Paper This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported. Beilstein-Institut 2009-03-12 /pmc/articles/PMC2686273/ /pubmed/19478964 http://dx.doi.org/10.3762/bjoc.5.9 Text en Copyright © 2009, Rowlands and Seacome https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Rowlands, Gareth J Seacome, Richard J Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title | Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title_full | Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title_fullStr | Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title_full_unstemmed | Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title_short | Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| title_sort | enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2686273/ https://www.ncbi.nlm.nih.gov/pubmed/19478964 http://dx.doi.org/10.3762/bjoc.5.9 |
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