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Synthesis of rigidified flavin–guanidinium ion conjugates and investigation of their photocatalytic properties

Flavin chromophores can mediate redox reactions upon irradiation by blue light. In an attempt to increase their catalytic efficacy, flavin derivatives bearing a guanidinium ion as oxoanion binding site were prepared. Chromophore and substrate binding site are linked by a rigid Kemp’s acid structure....

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Detalles Bibliográficos
Autores principales: Schmaderer, Harald, Bhuyan, Mouchumi, König, Burkhard
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2707025/
https://www.ncbi.nlm.nih.gov/pubmed/19590745
http://dx.doi.org/10.3762/bjoc.5.26