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A bonding model for gold(I) carbene complexes

The last decade has witnessed dramatic growth in the number of reactions catalyzed by electrophilic gold complexes. While proposed mechanisms often invoke the intermediacy of gold-stabilized cationic species, the nature of bonding in these intermediates remains unclear. Herein, we propose that the c...

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Detalles Bibliográficos
Autores principales: Benitez, Diego, Shapiro, Nathan D., Tkatchouk, Ekaterina, Wang, Yiming, Goddard, William A., Toste, F. Dean
Formato: Texto
Lenguaje:English
Publicado: 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748951/
https://www.ncbi.nlm.nih.gov/pubmed/20161015
http://dx.doi.org/10.1038/nchem.331