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A bonding model for gold(I) carbene complexes
The last decade has witnessed dramatic growth in the number of reactions catalyzed by electrophilic gold complexes. While proposed mechanisms often invoke the intermediacy of gold-stabilized cationic species, the nature of bonding in these intermediates remains unclear. Herein, we propose that the c...
Autores principales: | Benitez, Diego, Shapiro, Nathan D., Tkatchouk, Ekaterina, Wang, Yiming, Goddard, William A., Toste, F. Dean |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748951/ https://www.ncbi.nlm.nih.gov/pubmed/20161015 http://dx.doi.org/10.1038/nchem.331 |
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