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Discovery and synthetic applications of novel silicon-carbon bond cleavage reactions based on the coordination number change of organosilicon compounds
Some synthetically useful transformations of organosilicon compounds have been developed since the mid 1970s, based on the new concept that the silicon-carbon bonds are activated toward electrophilic cleavage via the formation of penta- and hexa-coordinate species. This review mainly consists of the...
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| Formato: | Texto |
| Lenguaje: | English |
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The Japan Academy
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2805510/ https://www.ncbi.nlm.nih.gov/pubmed/18941292 http://dx.doi.org/10.2183/pjab.84.123 |