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A short synthesis of (±)-cherylline dimethyl ether

A synthesis of (±)-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet–Spengler cyclization.

Detalles Bibliográficos
Autores principales: Kale, Bhima Y, Shinde, Ananta D, Sonar, Swapnil S, Shingate, Bapurao B, Kumar, Sanjeev, Ghosh, Samir, Venugopal, Soodamani, Shingare, Murlidhar S
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2839523/
https://www.ncbi.nlm.nih.gov/pubmed/20300502
http://dx.doi.org/10.3762/bjoc.5.80