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A short synthesis of (±)-cherylline dimethyl ether
A synthesis of (±)-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet–Spengler cyclization.
| Autores principales: | , , , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2839523/ https://www.ncbi.nlm.nih.gov/pubmed/20300502 http://dx.doi.org/10.3762/bjoc.5.80 |
| _version_ | 1782178957699842048 |
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| author | Kale, Bhima Y Shinde, Ananta D Sonar, Swapnil S Shingate, Bapurao B Kumar, Sanjeev Ghosh, Samir Venugopal, Soodamani Shingare, Murlidhar S |
| author_facet | Kale, Bhima Y Shinde, Ananta D Sonar, Swapnil S Shingate, Bapurao B Kumar, Sanjeev Ghosh, Samir Venugopal, Soodamani Shingare, Murlidhar S |
| author_sort | Kale, Bhima Y |
| collection | PubMed |
| description | A synthesis of (±)-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet–Spengler cyclization. |
| format | Text |
| id | pubmed-2839523 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-28395232010-03-17 A short synthesis of (±)-cherylline dimethyl ether Kale, Bhima Y Shinde, Ananta D Sonar, Swapnil S Shingate, Bapurao B Kumar, Sanjeev Ghosh, Samir Venugopal, Soodamani Shingare, Murlidhar S Beilstein J Org Chem Full Research Paper A synthesis of (±)-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet–Spengler cyclization. Beilstein-Institut 2009-12-16 /pmc/articles/PMC2839523/ /pubmed/20300502 http://dx.doi.org/10.3762/bjoc.5.80 Text en Copyright © 2009, Kale et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Kale, Bhima Y Shinde, Ananta D Sonar, Swapnil S Shingate, Bapurao B Kumar, Sanjeev Ghosh, Samir Venugopal, Soodamani Shingare, Murlidhar S A short synthesis of (±)-cherylline dimethyl ether |
| title | A short synthesis of (±)-cherylline dimethyl ether |
| title_full | A short synthesis of (±)-cherylline dimethyl ether |
| title_fullStr | A short synthesis of (±)-cherylline dimethyl ether |
| title_full_unstemmed | A short synthesis of (±)-cherylline dimethyl ether |
| title_short | A short synthesis of (±)-cherylline dimethyl ether |
| title_sort | short synthesis of (±)-cherylline dimethyl ether |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2839523/ https://www.ncbi.nlm.nih.gov/pubmed/20300502 http://dx.doi.org/10.3762/bjoc.5.80 |
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