Cargando…

Million-fold activation of the [Fe(2)(μ-O)(2)] diamond core for C-H bond cleavage

In biological systems, the cleavage of strong C–H bonds is often carried out by iron centers – such as the methane monooxygenase in methane hydroxylation – through dioxygen activation mechanisms. High valent species with [Fe(2)(μ-O)(2)] diamond cores are thought to act as the oxidizing moieties, but...

Descripción completa

Detalles Bibliográficos
Autores principales: Xue, Genqiang, De Hont, Raymond, Münck, Eckard, Que, Lawrence
Formato: Texto
Lenguaje:English
Publicado: 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2859466/
https://www.ncbi.nlm.nih.gov/pubmed/20414242
http://dx.doi.org/10.1038/nchem.586