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Million-fold activation of the [Fe(2)(μ-O)(2)] diamond core for C-H bond cleavage
In biological systems, the cleavage of strong C–H bonds is often carried out by iron centers – such as the methane monooxygenase in methane hydroxylation – through dioxygen activation mechanisms. High valent species with [Fe(2)(μ-O)(2)] diamond cores are thought to act as the oxidizing moieties, but...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2859466/ https://www.ncbi.nlm.nih.gov/pubmed/20414242 http://dx.doi.org/10.1038/nchem.586 |