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Benzyne arylation of oxathiane glycosyl donors

The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in situ from 1-aminobenzotriazole (1-ABT) and lead tetraacetate. Following sulfur arylation, glycosylation of acetate ions proceeded with high levels of stereoselectivity to afford α-glycosyl acetates in a...

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Detalles Bibliográficos
Autores principales: Fascione, Martin A, Turnbull, W Bruce
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2870982/
https://www.ncbi.nlm.nih.gov/pubmed/20485601
http://dx.doi.org/10.3762/bjoc.6.19