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Benzyne arylation of oxathiane glycosyl donors
The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in situ from 1-aminobenzotriazole (1-ABT) and lead tetraacetate. Following sulfur arylation, glycosylation of acetate ions proceeded with high levels of stereoselectivity to afford α-glycosyl acetates in a...
Autores principales: | Fascione, Martin A, Turnbull, W Bruce |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2870982/ https://www.ncbi.nlm.nih.gov/pubmed/20485601 http://dx.doi.org/10.3762/bjoc.6.19 |
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