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Size selective recognition of small esters by a negative allosteric hemicarcerand

A bis(resorcinarene) substituted 2,2′-bipyridine was found to bind weakly to small esters like ethyl acetate whereas more bulky esters were not recognized by this hemicarcerand. This size selective molecular recognition could be controlled by a negative cooperative allosteric effect: coordination of...

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Detalles Bibliográficos
Autores principales: Staats, Holger, Lützen, Arne
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2870999/
https://www.ncbi.nlm.nih.gov/pubmed/20485592
http://dx.doi.org/10.3762/bjoc.6.10