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Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylation

Seven polyoxazoline ligands were synthesized in high yield in a one-pot reaction by heating polycarboxylic acids or their esters and chiral β-amino alcohols under reflux with concomitant removal of water or the alcohol produced in the reaction. The method is much simpler and more efficient in compar...

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Detalles Bibliográficos
Autores principales: Li, Wei Jie, Xu, Zun Le, Qiu, Sheng Xiang
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2874315/
https://www.ncbi.nlm.nih.gov/pubmed/20502654
http://dx.doi.org/10.3762/bjoc.6.29