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Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
An abrupt change in internuclear Re–Re distances between {Re(6)} subunits in the carbon-centered [Re(12)μ(6)-CS(17)(CN)(6)](n−)complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field.(13)C NMR signal is sho...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Springer
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893436/ https://www.ncbi.nlm.nih.gov/pubmed/20596544 http://dx.doi.org/10.1007/s11671-009-9354-2 |