Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster

An abrupt change in internuclear Re–Re distances between {Re(6)} subunits in the carbon-centered [Re(12)μ(6)-CS(17)(CN)(6)](n−)complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field.(13)C NMR signal is sho...

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Detalles Bibliográficos
Autores principales: Gabuda, SP, Kozlova, SG, Mironov, Yu V, Fedorov, VE
Formato: Texto
Lenguaje:English
Publicado: Springer 2009
Materias:
Nano Perspectives
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893436/
https://www.ncbi.nlm.nih.gov/pubmed/20596544
http://dx.doi.org/10.1007/s11671-009-9354-2
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author Gabuda, SP
Kozlova, SG
Mironov, Yu V
Fedorov, VE
author_facet Gabuda, SP
Kozlova, SG
Mironov, Yu V
Fedorov, VE
author_sort Gabuda, SP
collection PubMed
description An abrupt change in internuclear Re–Re distances between {Re(6)} subunits in the carbon-centered [Re(12)μ(6)-CS(17)(CN)(6)](n−)complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field.(13)C NMR signal is shown to change over ~400 ppm (~37G) for μ(6)-C atom together withn. Thereby, the metal cluster [Re(12)μ(6)-CS(17)(CN)(6)](n−)can be considered as a perspective model of a molecular switch.
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spelling pubmed-28934362010-06-30 Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster Gabuda, SP Kozlova, SG Mironov, Yu V Fedorov, VE Nanoscale Res Lett Nano Perspectives An abrupt change in internuclear Re–Re distances between {Re(6)} subunits in the carbon-centered [Re(12)μ(6)-CS(17)(CN)(6)](n−)complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field.(13)C NMR signal is shown to change over ~400 ppm (~37G) for μ(6)-C atom together withn. Thereby, the metal cluster [Re(12)μ(6)-CS(17)(CN)(6)](n−)can be considered as a perspective model of a molecular switch. Springer 2009-05-30 /pmc/articles/PMC2893436/ /pubmed/20596544 http://dx.doi.org/10.1007/s11671-009-9354-2 Text en Copyright ©2009 to the authors
spellingShingle Nano Perspectives
Gabuda, SP
Kozlova, SG
Mironov, Yu V
Fedorov, VE
Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title_full Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title_fullStr Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title_full_unstemmed Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title_short Electronic Switch in the Carbon-Centered [Re(12)CS(17)(CN)(6)](n−)Nanocluster
title_sort electronic switch in the carbon-centered [re(12)cs(17)(cn)(6)](n−)nanocluster
topic Nano Perspectives
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893436/
https://www.ncbi.nlm.nih.gov/pubmed/20596544
http://dx.doi.org/10.1007/s11671-009-9354-2
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