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Nonlinear Rheology of Unentangled Polymer Melts Reinforced with High Concentration of Rigid Nanoparticles
A scaling model is presented to analyze the nonlinear rheology of unentangled polymer melts filled with high concentration of small spherical particles. Assuming the majority of chains to be reversibly adsorbed to the surface of the particles, we show that the emergence of nonlinearity in the viscoe...
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| Formato: | Texto |
| Lenguaje: | English |
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Springer
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893936/ https://www.ncbi.nlm.nih.gov/pubmed/20672142 http://dx.doi.org/10.1007/s11671-010-9557-6 |