Cargando…

Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysi...

Descripción completa

Detalles Bibliográficos
Autores principales: Kawasaki, Tsuneomi, Hohberger, Christiane, Araki, Yuko, Hatase, Kunihiko, Beckerle, Klaus, Okuda, Jun, Soai, Kenso
Formato: Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898645/
https://www.ncbi.nlm.nih.gov/pubmed/19753377
http://dx.doi.org/10.1039/b912813a