Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysi...

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Detalles Bibliográficos
Autores principales: Kawasaki, Tsuneomi, Hohberger, Christiane, Araki, Yuko, Hatase, Kunihiko, Beckerle, Klaus, Okuda, Jun, Soai, Kenso
Formato: Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2009
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898645/
https://www.ncbi.nlm.nih.gov/pubmed/19753377
http://dx.doi.org/10.1039/b912813a
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author Kawasaki, Tsuneomi
Hohberger, Christiane
Araki, Yuko
Hatase, Kunihiko
Beckerle, Klaus
Okuda, Jun
Soai, Kenso
author_facet Kawasaki, Tsuneomi
Hohberger, Christiane
Araki, Yuko
Hatase, Kunihiko
Beckerle, Klaus
Okuda, Jun
Soai, Kenso
author_sort Kawasaki, Tsuneomi
collection PubMed
description Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis.
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spelling pubmed-28986452011-09-26 Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis Kawasaki, Tsuneomi Hohberger, Christiane Araki, Yuko Hatase, Kunihiko Beckerle, Klaus Okuda, Jun Soai, Kenso Chem Commun (Camb) Chemistry Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis. Royal Society of Chemistry 2009-10-07 2009-08-21 /pmc/articles/PMC2898645/ /pubmed/19753377 http://dx.doi.org/10.1039/b912813a Text en This journal is © The Royal Society of Chemistry 2009 http://creativecommons.org/licenses/by-nc/2.0/uk/ This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/2.0/uk/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Kawasaki, Tsuneomi
Hohberger, Christiane
Araki, Yuko
Hatase, Kunihiko
Beckerle, Klaus
Okuda, Jun
Soai, Kenso
Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title_full Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title_fullStr Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title_full_unstemmed Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title_short Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
title_sort discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898645/
https://www.ncbi.nlm.nih.gov/pubmed/19753377
http://dx.doi.org/10.1039/b912813a
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