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Tetra­kis(N,N-diethyl­carbamato)titanium(IV)

The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca­hedral and the O—C—O angles of the carbamate ligands are slightly compressed [range 115.3 (...

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Detalles Bibliográficos
Autores principales: Straessler, Nicholas A., Caudle, M. Tyler, Groy, Thomas L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914932/
https://www.ncbi.nlm.nih.gov/pubmed/21200619
http://dx.doi.org/10.1107/S160053680705742X