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Tetrakis(N,N-diethylcarbamato)titanium(IV)
The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodecahedral and the O—C—O angles of the carbamate ligands are slightly compressed [range 115.3 (...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914932/ https://www.ncbi.nlm.nih.gov/pubmed/21200619 http://dx.doi.org/10.1107/S160053680705742X |
| _version_ | 1782184819360268288 |
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| author | Straessler, Nicholas A. Caudle, M. Tyler Groy, Thomas L. |
| author_facet | Straessler, Nicholas A. Caudle, M. Tyler Groy, Thomas L. |
| author_sort | Straessler, Nicholas A. |
| collection | PubMed |
| description | The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodecahedral and the O—C—O angles of the carbamate ligands are slightly compressed [range 115.3 (2)–116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36. |
| format | Text |
| id | pubmed-2914932 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149322010-12-30 Tetrakis(N,N-diethylcarbamato)titanium(IV) Straessler, Nicholas A. Caudle, M. Tyler Groy, Thomas L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodecahedral and the O—C—O angles of the carbamate ligands are slightly compressed [range 115.3 (2)–116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914932/ /pubmed/21200619 http://dx.doi.org/10.1107/S160053680705742X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Straessler, Nicholas A. Caudle, M. Tyler Groy, Thomas L. Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title | Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title_full | Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title_fullStr | Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title_full_unstemmed | Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title_short | Tetrakis(N,N-diethylcarbamato)titanium(IV) |
| title_sort | tetrakis(n,n-diethylcarbamato)titanium(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914932/ https://www.ncbi.nlm.nih.gov/pubmed/21200619 http://dx.doi.org/10.1107/S160053680705742X |
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