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An ionic organic–inorganic hybrid: tetrakis[bis(1,10-phenanthroline)copper(I)] dodecatungstophosphate(V)
Single crystals of the title polyoxometallate-based organic–inorganic hybrid, [Cu(C(12)H(8)N(2))(2)](4)[SiW(12)O(40)], were grown under hydrothermal conditions. The discrete [SiW(12)O(40)](4−) anions are of the Keggin type and are packed in a slightly distorted orthorhombic F-centred mode, with t...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915059/ https://www.ncbi.nlm.nih.gov/pubmed/21200465 http://dx.doi.org/10.1107/S1600536807062903 |