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(+)-(1S,5R,10S)-11,11-Dimethyl-4-oxatricyclo[8.4.0.0(1,5)]tetradecane-3,12-dione
The title compound, C(15)H(22)O(3), was prepared via amino-acid-promoted Robinson annulation followed by tandem Pd/C-mediated hydrogenation and oxidative cyclization. This product was instrumental in determining the feasibility of a stereocontrolled hydrogenation in which the directing hydroxyl grou...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915339/ https://www.ncbi.nlm.nih.gov/pubmed/21200853 http://dx.doi.org/10.1107/S1600536807066159 |