Optimized Synthesis of Tetrafluoroterephthalic Acid: A Versatile Linking Ligand for the Construction of New Coordination Polymers and Metal-Organic Frameworks

[Image: see text] Pure 2,3,5,6-tetrafluoroterephthalic acid (H(2)tfBDC) is obtained in high yields (95%) by reacting 1,2,4,5-tetrafluorobenzene with a surplus (>2 equiv) of n-butyllithium in tetrahydrofuran (THF) and subsequent carbonation with CO(2) without any extensive purification procedure....

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Detalles Bibliográficos
Autores principales: Orthaber, Andreas, Seidel, Christiane, Belaj, Ferdinand, Albering, Jörg H., Pietschnig, Rudolf, Ruschewitz, Uwe
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2010
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2953279/
https://www.ncbi.nlm.nih.gov/pubmed/20845925
http://dx.doi.org/10.1021/ic1009829

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2953279/
https://www.ncbi.nlm.nih.gov/pubmed/20845925
http://dx.doi.org/10.1021/ic1009829

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