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Hydrogen Exchange Equilibria in Glutathione Radicals: Rate Constants
[Image: see text] The reduction of oxidized glutathione GSSG by hydrated electrons and hydrogen atoms to form GSSG(•−) is quantitative. The radical anion dissociates into GS(•) and GS(−), and the S-centered radical subsequently abstracts a hydrogen intramolecularly. We observe sequential development...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956374/ https://www.ncbi.nlm.nih.gov/pubmed/20882988 http://dx.doi.org/10.1021/tx100185k |