Systematic investigations on the reduction of 4-aryl-4-oxoesters to 1-aryl-1,4-butanediols with methanolic sodium borohydride

4-Aryl-4-oxoesters undergo facile reduction of both the keto and the ester groups with methanolic NaBH(4) at room temperature to yield the corresponding 1-aryl-1,4-butanediols whereas 4-alkyl-4-oxoesters furnish the corresponding 1,4-butanolides via selective reduction of the keto moiety. Results of...

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Detalles Bibliográficos
Autores principales: Chaudhuri, Subrata Kumar, Saha, Manabendra, Saha, Amit, Bhar, Sanjay
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956461/
https://www.ncbi.nlm.nih.gov/pubmed/20978613
http://dx.doi.org/10.3762/bjoc.6.94

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2956461/
https://www.ncbi.nlm.nih.gov/pubmed/20978613
http://dx.doi.org/10.3762/bjoc.6.94

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